Investigation and Preparation of Hydrolytically Stable Aminosilane-derived Layers on Silica Surfaces
dc.contributor | Knight, Jeffrey | |
dc.contributor | Jayathilake, Himali | |
dc.contributor.advisor | Chen, Wei | |
dc.contributor.author | Zhu, Mojun | |
dc.date.accessioned | 2011-05-12T18:34:20Z | |
dc.date.available | 2011-05-12T18:34:20Z | |
dc.date.gradyear | 2011 | en_US |
dc.date.issued | 2011-05-12 | |
dc.description.abstract | Aminosilanes are commonly used to functionalize silica substrates. The hydrolytic stability of aminosilane-derived layers is a major consideration in choosing suitable reagents for aqueous applications. We recently reported that aminosilane-derived layers prepared with the most widely used silane coupling agents, 3-aminopropylalkoxysilanes, suffer extensive loss upon exposure to water at moderate temperatures. This is likely caused by siloxane bond hydrolysis catalyzed by the amine functionality via the formation of a stable five-membered intermediate. In this study, we evaluated the performances of five silane coupling agents, 3-aminopropyltriethoxysilane (APTES), 3-aminopropyltrimethoxysilane (APTMS), N-(6-aminohexyl)aminomethyltriethoxysilane (AHAMTES), N-(2-aminoethyl)-3-aminopropyltriethoxysilane (AEAPTES), and N-(2-aminoethyl)-3-aminopropyltrimethoxysilane (AEAPTMS). They have the general structures of NH2(CH2)kSi(OR)3 and NH2(CH2)nNH(CH2)mSi(OR)3 , where R represents either a methyl or an ethyl group. Silanization was carried out on silicon wafers in anhydrous toluene or in the vapor phase. The hydrolytic stability of aminosilane-derived layers was correlated with the reaction conditions and the silane structural features. | en_US |
dc.description.sponsorship | Chemistry | en_US |
dc.identifier.uri | http://hdl.handle.net/10166/850 | |
dc.language.iso | en_US | en_US |
dc.rights | Attribution 3.0 Unported | |
dc.rights.restricted | public | |
dc.rights.uri | http://creativecommons.org/licenses/by/3.0/ | |
dc.subject | aminosilane | en_US |
dc.subject | silanization | en_US |
dc.title | Investigation and Preparation of Hydrolytically Stable Aminosilane-derived Layers on Silica Surfaces | en_US |
dc.type | Thesis | en_US |
mhc.degree | Undergraduate | en_US |
mhc.institution | Mount Holyoke College |
Files
Original bundle
1 - 3 of 3
Loading...
- Name:
- Title_MojunZhu.pdf
- Size:
- 19.51 KB
- Format:
- Adobe Portable Document Format
- Description:
- Title
Loading...
- Name:
- Abstract_MojunZhu.pdf
- Size:
- 73.98 KB
- Format:
- Adobe Portable Document Format
- Description:
- Abstract
Loading...
- Name:
- Thesis_MojunZhu.pdf
- Size:
- 846.31 KB
- Format:
- Adobe Portable Document Format
- Description:
- Main article
License bundle
1 - 1 of 1
No Thumbnail Available
- Name:
- license.txt
- Size:
- 1.82 KB
- Format:
- Item-specific license agreed upon to submission
- Description: